The Japanese Consumer Affairs Agency (CAA) maintains an accident information database that publicly catalogues incidents related to high-concentration hydrogen inhalation devices. These are recorded as incidents involving explosion or ignition during real-world inhalation use.
Aggregating the published cases:
These cases demonstrate that the argument "100% pure hydrogen exceeds the UFL and is therefore safe" cannot explain the documented harms. The combination of boundary-layer flammable-range crossover, mixing within the airway, and hydrogen's very low minimum ignition energy produces accidents the designers did not anticipate (→ Inhalation concentration).
Individual case IDs and details should be consulted directly against the database. This page aggregates trends; the primary data lives at the CAA and should be cited directly.
https://h2-papers.org/en/safety-notes/accident-cases