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1-[(4-Bromo-phen-yl)(morpholin-4-yl)meth-yl]naphthalen-2-ol.

1-[(4-ブロモフェニル)(モルホリン-4-イル)メチル]ナフタレン-2-オールの結晶構造解析

other not specified not assessed

Abstract

The crystal structure of C21H20BrNO2, synthesized via condensation of 4-bromobenzaldehyde, 2-naphthol, and morpholine, was determined. An intramolecular O-H···N hydrogen bond closes a six-membered ring, stabilizing the molecular conformation. The dihedral angle between the naphthalene ring system and the benzene ring measures 76.72(8)°. Intermolecular packing features include short O-H···O contacts of 2.59 Å between centrosymmetrically related molecules, as well as C-H···O interactions that generate an R2(2)(14) hydrogen-bond motif.

Bibliographic

Authors
Zhao Q
Journal
Acta Crystallogr Sect E Struct Rep Online
Year
2012 (2012-02-01)
PMID
22347125
DOI
10.1107/S1600536812002620
PMC
PMC3275269

Delivery context

The delivery route is not clearly identifiable from this paper. For hydrogen intake, inhalation is the most efficient route; inhalation, however, carries explosion risk (empirical LFL of 10%; high-concentration devices are not recommended).

Safety notes

The delivery route is not clearly identifiable from this paper. For hydrogen intake, inhalation is the most efficient route; inhalation, however, carries explosion risk (empirical LFL of 10%; high-concentration devices are not recommended).

See also:

Cite as: H2 Papers — PMID 22347125. https://h2-papers.org/en/papers/22347125
Source: PubMed PMID 22347125