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6,8-Dihy-droxy-8a-methyl-3,5-dimethyl-idenedeca-hydro-naphtho-[2,3-b]furan-2(3H)-one.

中国薬用植物由来のユーデスマノライド系化合物の結晶構造解析

other not specified not assessed

Abstract

This study reports the crystal structure of C15H20O4, a eudesmanolide-type sesquiterpene lactone obtained from the Chinese medicinal plant Carpesium triste Maxim. The molecular framework consists of three rings: two fused six-membered rings adopting chair conformations and one five-membered ring in a flattened envelope conformation. Within the crystal lattice, two hydroxyl groups participate in both intramolecular and intermolecular O-H···O hydrogen bonding. The hydrogen atoms associated with these groups exhibit positional disorder, with site-occupation factors of 0.5. Intermolecular hydrogen bonds organize the molecules into chains extending along the [010] direction.

Bibliographic

Authors
Liu TT, Wu HB, Wang WS
Journal
Acta Crystallogr Sect E Struct Rep Online
Year
2012 (2012-11-01)
PMID
23284548
DOI
10.1107/S160053681204425X
PMC
PMC3515328

Delivery context

The delivery route is not clearly identifiable from this paper. For hydrogen intake, inhalation is the most efficient route; inhalation, however, carries explosion risk (empirical LFL of 10%; high-concentration devices are not recommended).

Safety notes

The delivery route is not clearly identifiable from this paper. For hydrogen intake, inhalation is the most efficient route; inhalation, however, carries explosion risk (empirical LFL of 10%; high-concentration devices are not recommended).

See also:

Cite as: H2 Papers — PMID 23284548. https://h2-papers.org/en/papers/23284548
Source: PubMed PMID 23284548